Language selection

Search

Patent 3012166 Summary

Third-party information liability

Some of the information on this Web page has been provided by external sources. The Government of Canada is not responsible for the accuracy, reliability or currency of the information supplied by external sources. Users wishing to rely upon this information should consult directly with the source of the information. Content provided by external sources is not subject to official languages, privacy and accessibility requirements.

Claims and Abstract availability

Any discrepancies in the text and image of the Claims and Abstract are due to differing posting times. Text of the Claims and Abstract are posted:

  • At the time the application is open to public inspection;
  • At the time of issue of the patent (grant).
(12) Patent: (11) CA 3012166
(54) English Title: METHOD FOR ESTIMATING DYNAMIC STATE VARIABLES IN AN ELECTROLYTIC CELL SUITABLE FOR THE HALL-HEROULT ELECTROLYSIS PROCESS
(54) French Title: PROCEDE D'ESTIMATION DE VARIABLES D'ETAT DYNAMIQUES DANS UNE CELLULE ELECTROLYTIQUE CONVENANT POUR LE PROCEDE D'ELECTROLYSE HALL-HEROULT
Status: Granted and Issued
Bibliographic Data
(51) International Patent Classification (IPC):
  • C25C 03/20 (2006.01)
  • C25C 03/06 (2006.01)
  • G05B 13/04 (2006.01)
  • G05B 17/02 (2006.01)
(72) Inventors :
  • YAO, YUCHEN (Australia)
  • CHEUNG, CHEUK-YI (Australia)
  • BAO, JIE (Australia)
  • WELCH, BARRY (New Zealand)
  • SKYLLAS-KAZACOS, MARIA (Australia)
  • AKHMETOV, SERGEY (United Arab Emirates)
  • BANJAB, ALI JASIM (United Arab Emirates)
(73) Owners :
  • DUBAI ALUMINIUM PJSC
  • NEWSOUTH INNOVATIONS PTY LIMITED
(71) Applicants :
  • DUBAI ALUMINIUM PJSC (United Arab Emirates)
  • NEWSOUTH INNOVATIONS PTY LIMITED (Australia)
(74) Agent: FASKEN MARTINEAU DUMOULIN LLP
(74) Associate agent:
(45) Issued: 2023-09-05
(86) PCT Filing Date: 2017-02-08
(87) Open to Public Inspection: 2017-08-24
Examination requested: 2022-01-05
Availability of licence: N/A
Dedicated to the Public: N/A
(25) Language of filing: English

Patent Cooperation Treaty (PCT): Yes
(86) PCT Filing Number: PCT/IB2017/050661
(87) International Publication Number: IB2017050661
(85) National Entry: 2018-07-20

(30) Application Priority Data:
Application No. Country/Territory Date
1602613.0 (United Kingdom) 2016-02-15

Abstracts

English Abstract

Method of producing aluminium in an electrolytic cell using the Hall-Héroult electrolysis process, said method comprising the following steps: -dividing said cell into at least n subsystems, -for each subsystem, estimating the local value of at least one target or output parameter on the basis of the value of the measurement of at least one input parameter, -modifying at least one of said input parameters in the cell by exerting a physical action upon the cell, if at least one estimated value of said output parameter, for at least one subsystem, is substantially different from another estimated value of said output parameter for another subsystem.


French Abstract

L'invention porte sur un procédé de fabrication d'aluminium dans une cellule électrolytique utilisant le procédé d'électrolyse Hall-Héroult, ledit procédé comprenant les étapes suivantes : la division de ladite cellule en au moins n sous-systèmes ; pour chaque sous-système, l'estimation de la valeur locale d'au moins un paramètre cible ou de sortie sur la base de la valeur de la mesure d'au moins un paramètre d'entrée ; la modification d'au moins un desdits paramètres d'entrée dans la cellule en exerçant une action physique sur la cellule, si au moins une valeur estimée dudit paramètre de sortie, pour au moins un sous-système, est sensiblement différente d'une autre valeur estimée dudit paramètre de sortie pour un autre sous-système.

Claims

Note: Claims are shown in the official language in which they were submitted.


15
CLAIMS
1. A method of producing aluminium in an electrolytic cell using the Hall-
Héroult
electrolysis process, said cell comprising
- a cathode
forming the bottom of said electrolytic cell and comprising a plurality of
parallel cathode blocks, each cathode block carrying at least one current
collector
bar and two electrical connections points,
- a lateral lining defining together with the cathode a volume containing a
liquid
electrolyte and a liquid metal resulting from the Hall-Héroult electrolysis
process,
said cathode and lateral lining being contained in an outer metallic shell,
- a plurality of anode assemblies suspended above the cathode, each anode
assembly comprising at least one anode and a metallic anode rod connected to
an
anode busbar,
- a plurality of alumina feeders by which alumina powder is fed into a liquid
bath,
said method comprising the following steps:
- dividing said cell into at least n subsystems,
- for each subsystem, estimating the local value of at least one target or
output
parameter on the basis of the value of the measurement of at least one input
parameter,
- modifying at least one of said input parameters in the cell by exerting a
physical
action upon the cell, if at least one estimated value of said output
parameter, for at
least one subsystem, is substantially different from another estimated value
of
said output parameter for another subsystem.
2. The method according to claim 1, wherein said output parameter is the local
alumina
concentration in the subsystem and/or the alumina dissolution rate and/or the
local anode-
cathode distance in the subsystem.
3. The method according to claim 1 or 2, wherein
- said input parameter is selected from the group consisting of: currents of
anodes in the
subsystem, anode busbar movement in the subsystem, cell voltage in the
subsystem,
alumina dumps in the subsystem and ACD change rate,
- and/or said input parameter is the output of a previous estimate of one or
more of local
variables.
4. The method according to any of claims 1 to 3, wherein said input parameter
is the
individual anode current determined for each anode in the subsystem.
Date Recue/Date Received 2023-02-21

16
5. The method according to any of claims 1 to 4, wherein n is chosen between 2
and 16.
6. The method according to claim 5, wherein n is equal to 4.
7. The method according to any of claims 1 to 6, characterized in that said
subsystems
correspond to sectors of substantially same length, divided along the main
dimension of the
cell.
8. The method according to any of claims 1 to 7, wherein said output parameter
is the local
concentration of alumina in the bath, and wherein said physical action
comprises increasing
or decreasing the alumina dump in the subsystem in which the estimated
concentration of
alumina in the bath is inferior or superior, respectively, to a predetermined
target value.
9. The method according to any of claims 1 to 8, wherein said output parameter
is the anode
¨ cathode distance, and wherein said physical action comprises increasing or
decreasing the
anode ¨ cathode distance, when the estimated anode ¨ cathode distance is
inferior or
superior, respectively, to a predetermined target value.
10. The method according to any of claims 1 to 9, characterized in that it
comprises the
following stages,
- measuring at least one value, called here "level 1 measured value", of said
input parameter
for the whole cell,
- obtaining at least one value, called here "level 1 estimated value", of
said output parameter,
on the basis of said level 1 measured value, using a mathematical observer;
- dividing said cell into at least two subsystems called "level 2 subsystems",
- for each level 2 subsystem, measuring at least one value, called "level 2
measured value",
of said input parameter,
- for each level 2 subsystem, obtaining at least one value, called "level 2
estimated value", of
said output parameter, on the basis both of said level 2 measured value and of
said level 1
estimated value, using said mathematical observer.
11. The method according to any of claims 1 to 10, characterized in that it
further comprises
the following steps, carried out in a recursive or cascaded way:
- dividing said cell into at least 2" subsystems of level n,
- for each subsystem of level n: measuring at least one value, called "level n
measured
value", of said input parameter
- for each subsystem of level n: obtaining at least one value, called "level n
estimated
value", of said output parameter, on the basis both of said level n measured
value
and of said level (n-1) estimated value, using said mathematical observer.
Date Recue/Date Received 2023-02-21

17
12. The method according to claim 11, characterized in that said mathematical
observer is of
the Kalman filter-type.
13. An electrolytic cell suitable for the Hall-Héroult electrolysis process,
said cell comprising
- a cathode forming the bottom of said electrolytic cell and comprising a
plurality of
parallel cathode blocks, each cathode block carrying at least one current
collector bar
and two electrical connections points,
- a lateral lining defining together with the cathode a volume containing a
liquid
electrolyte and a liquid metal resulting from the Hall-Héroult electrolysis
process,
said cathode and lateral lining being contained in an outer metallic shell,
- a plurality of anode assemblies suspended above the cathode, each anode
assembly
comprising at least one anode and a metallic anode rod connected to an anode
busbar,
- a plurality of alumina feeders by which alumina powder is fed into a
liquid bath,
and said electrolytic cell being characterized in that it comprises specific
means for
carrying out the method according to any of claims 1 to 12.
14. The electrolytic cell according to claim 13, characterized in that said
specific means
comprise a specifically programmed microprocessor.
15. The electrolytic cell according to claim 12 or 14, characterized in that
said cell
comprises means to determine individual anode currents for each anode.
Date Recue/Date Received 2023-02-21

Description

Note: Descriptions are shown in the official language in which they were submitted.


CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
1
Method for estimating dynamic state variables in an electrolytic cell suitable
for the
Hall-Fleroult electrolysis process
Technical field of the invention
The invention relates to the field of fused salt electrolysis, and more
precisely to the
monitoring of Hall-Heroult process for making aluminium by fused salt
electrolysis. In
particular, the invention relates to a novel method of monitoring aluminium
smelting
process. This method is based on a particular approach of anode current
measurement
using digital communication for easy wiring, installation and maintenance, and
applies a
Kalman filter type state observer to a dynamic model of the process for the
estimation of
unmeasured process variables.
Prior art
The Hall-Heroult process is the only continuous industrial process for
producing metallic
.. aluminium from aluminium oxide. Aluminium oxide (A1203) is dissolved in
molten cryolite
(Na3AIF6), and the resulting mixture (typically at a temperature comprised
between 940 C
and 970 C) acts as a liquid electrolyte in an electrolytic cell. An
electrolytic cell (also called
"pot") used for the Hall-Heroult process typically comprises a steel shell, a
lining usually
made from refractory bricks, a cathode usually covering the whole bottom of
the pot (and
which is usually made from graphite, anthracite or a mixture of both), and a
plurality of
anodes (usually made from carbon) that plunge into the liquid electrolyte.
Anodes and
cathodes are connected to external busbars. An electrical current is passed
through the
cell (typically at a voltage between 3.7 V to 5 V) which splits the aluminium
oxide in
aluminium ions and oxygen ions. The oxide ions are reduced to oxygen at the
anode, said
oxygen reacting with the carbon of the anode. The aluminium ions move to the
cathode
where they accept electrons supplied by the cathode; the resulting metallic
aluminium is
not miscible with the liquid electrolyte, has a higher density than the liquid
electrolyte and
will thus accumulate as a liquid metal pad on the cathode surface from where
it needs to
be removed from time to time, usually by suction.
In order to decrease the capital cost per ton of production capacity of
aluminum, the size
of aluminium reduction cells, as well as the number of anodes per cell, tends
to increase.
Thus, keeping the cell in a balanced state has become increasingly important.
One of the
crucial process variables is the alumina content and its uniformity in the
cell. The
concentration of dissolved alumina needs to be regulated in a limited range to
prevent
anode effect and the formation of sludge, and its distribution affects the
balance of the
cell. As alumina is consumed during the electrolysis process, it must be added
regularly,
through so-called feeders. Feeders are most often associated with crust-
breakers that

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
2
provide a hole into the crust of solidified liquid bath (containing a mixture
of cryolite and
alumina) that forms on the top of the electrolyte layer; the feeder then dumps
alumina
powder through that hole into the liquid bath.
However, the concentration of dissolved alumina in the electrolyte of an
electrolytic cell
does not lend itself to direct or continuous measurement during operation: a
sample for
chemical analysis is usually taken several times per weeks but not necessarily
each day ¨
this would be totally insufficient to identify for instance a drift of alumina
concentration due
to faulty equipment, such as malfunctioning of the crust breaker or feeder, or
a leak of the
feeder. What can be measured directly and continuously is cell resistance: the
currently
available control strategies of the process, such as the ones described in US
4,654,129
and US 4,766,552, are largely dependent on the cell resistance. The cell
resistance
represents a combination of the average anode-cathode distance (ACD), global
bath
composition and bath properties in the cell, which is not able to reflect the
spatial
variations in the cell. As a consequence, approaches based on cell resistance
would leave
localised abnormalities undetected until they become severe and apparent on
the cell
resistance.
In order to improve the cell control, and, in particular, to identify
defective feeders or crust
breakers early, it would be desirable to gain localized information on
operating parameters
within an electrolysis cell. As an example, it is known (see K. Rye et al.,
"Current
redistribution among individual anode carbons in a Hall-Heroult prebake cell
at low
alumina concentration", TMS Light Metals 1998, p. 241-246) that anodes located
in areas
where the concentration of dissolved alumina is low take less current than
anodes in
areas where the alumina concentration is higher. Various methods and devices
for
measurement of the current through each individual anode have been proposed.
These
methods include the calculation of the anode currents from voltage drop
measurement
across a length of conductor (see US 4,786,379 and WO 94/002859), and the use
of Hall
Effect sensors (see J.W. Evans and N. Urata ("Wireless and Non-Contacting
Measurement of Individual Anode Currents in Hal-Heroult Pots; Experience and
Benefits",
Light Metals 2012, TMS, p. 939-942).
The measurement of anode current distribution in a cell provides a general
guide to the
cell conditions in the vicinity of each anode, but a quantitative analysis
allowing to obtain
localized information on the electrolysis process in a Hall-Heroult cell is
very difficult. This
is because the variation and interactions of anode currents are complicated,
for example,
through a number of ways as follows:

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
3
(i) While the anode current affects local cell conditions, it is also affected
by these
conditions.
(ii) Variation in one anode current will affect others due to the controlled
line current.
(iii) Anode current represents a combination of localized variables. As they
are coupled,
the separation of one variable from others is not easy.
(iv) There are mass and energy transfers within the cell that will cause
spatial variations,
which, in turn, can alter the anode current distribution.
Therefore, anode current needs to be treated as part of a dynamic system,
where the
variations of process variables are taken into account.
State observer is a mathematical tool in system science that is used to
estimate the
internal states of a dynamic system based on the measured inputs and outputs
of the
system. It provides the basic structure to the process monitoring and control
methods in a
wide range of industrial applications.
Kalman filter-type state observer has been disclosed in a number of
publications, such as
US 4,814,050 and WO 2009/067019. In these approaches, the state estimation is
based
on the whole cell, thus the spatial variations are not accounted for. The use
of Kalman
filter-type state observer with anode currents in Hall-Heroult cells has been
discussed in a
certain number of papers: Jakobsen et.al., "Estimating alumina concentration
distribution
in aluminium electrolysis cells", Proc. 10th IFAC Symposium on Automation in
Mining,
Mineral and Metal Processing, p.253-258 (2001); K. Hestetun, M. Hovd,
"Dectecting
abnormal feed rate in aluminium electrolysis using extended Kalman filter", I
FAC World
Congress, Praha 2005; and K. Hestetun, M. Hovd, "Detection of abnormal alumina
feed
rate in aluminium electrolysis cells using state and parameter estimation",
16th European
Symposium on Computer Aided Process Engineering and 9th International
Symposium on
Process Systems Engineering, Elsevier 2006, p.1557-1562. These papers
attempted to
estimate local cell conditions using the measured individual anode current.
However, as
pointed out by the authors, the ACD change cannot be accommodated in these
methods.
In fact, the initial conditions need to be carefully chosen in the mentioned
papers, and are
assumed to be constant, which deviates the purpose of state estimation.
The problem that the present invention endeavors to resolve is therefore to
propose an
improved method for monitoring of aluminium reduction cells which can deal
with the
interactions between spatial process variables and interaction between current
in different
anodes. Moreover, the invention wishes to provide such a method, which allows
for

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
4
different initial estimation of states and can be used effectively online. And
eventually, the
method for monitoring aluminium reduction cells should be simple, reliable and
robust in
view of its use in an industrial environment.
Object of the invention
The present invention is devoted to the estimation of spatial alumina
concentration and
local ACD using a multi-stage state observer. In each stage, the cell is
discretized
successively into subsystems, with each containing a number of anodes. The
states in
each subsystem are estimated based on a dynamic model using the measurement of
anode currents associated with the subsystem, measurement of cell voltage,
feeding
information and the estimation from the previous stage.
The dynamic model used in each stage of the state observer has the following
features:
1. It includes the dynamics of alumina addition, dissolution and consumption.
The addition
of the alumina is referred to the dumps from the feeders. The dissolution of
the alumina
follows a specific rate equation and the consumption of the dissolved alumina
can be
obtained from Faraday's equation. In addition, the model also deals with the
mass transfer
between subsystems due to the induced bath flow.
2. It includes the dynamics of ACD variation, which is associated with the
consumption of
carbon anodes, the beam movement, and the accumulation of liquid aluminium at
the
cathode.
3. It calculates cell voltage from a semi-empirical equation, which is a
function of anode
current, alumina concentration, ACD and other parameters. Cell voltage
equations are
known by a person skilled in the art and can be found in the standard textbook
of
Grjotheim, K. & Kvande, H. 1993, "Introduction to aluminium electrolysis:
understanding
the Hall-Hero ult process", Aluminium-Verlag, Dusseldorf, or in Haupin's
paper,
"Interpreting the components of cell voltage", TMS Light Metals 1998, p. 531-
537.
The model can be represented as the following discrete-time state-space form:
N +1
cun = fl(Cun,kun, feedN ,M
N+1 r N =N AA-
Cd = 2 (Cd , mun,/ , (42 )
ACDN+1 = f3(ACDN ,BAIN )

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
vN = h(S/,ACDN,iN,O)
(equation 1)
where N represents the time step, cõ is the concentration of the undissolved
alumina, kõ
is the effective rate constant for the dissolution of alumina, cd is the
concentration of the
5
dissolved alumina, M is the mass of bath in the subsystem, BM is the variation
in beam
movement, i is the total anode current flowing into the subsystem impacting
the
consumption of dissolved alumina and the rate of change of ACD, d1 and d2
represent the
mass transfer between relevant subsystems, v is the cell voltage, h represents
the voltage
equation, e represents the relevant process parameters.
The estimation of spatial alumina concentration and ACD is achieved by a state
observer.
In an advantageous embodiment the observer is of Kalman filter type, which
estimates the
state variables as well as their uncertainties, and sequentially updates the
estimation
when the next measurement is available, based on a weighted average. According
to an
essential feature of the present invention, the estimation result from one
stage is used an
input in the next stage.
A first object of the invention is a method of producing aluminium in an
electrolytic cell
using the Hall-Heroult electrolysis process, said cell comprising
- a cathode forming the bottom of said electrolytic cell and comprising a
plurality
of parallel cathode blocks, each cathode block carrying at least one current
collector bar and two electrical connections points,
- a lateral lining defining together with the cathode a volume containing
the liquid
electrolyte and the liquid metal resulting from the Hall-Heroult electrolysis
process,
said cathode and lateral lining being contained in an outer metallic shell,
- a plurality of anode assemblies suspended above the cathode, each anode
assembly comprising at least one anode and a metallic anode rod connected to
an anode busbar (so-called "anode beam"),
- a plurality of alumina feeders by which alumina powder is fed into the
liquid
bath,
said method comprising the following steps:
- dividing said cell into at least n subsystems,
- for each subsystem, estimating the local value of at least one target or
output
parameter on the basis of the value of the measurement of at least one input
parameter,

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
6
- modifying at least one of said input parameters in the cell by exerting a
physical
action upon the cell, if at least one estimated value of said output
parameter, for
at least one subsystem, is substantially different from another estimated
value
of said output parameter for another subsystem.
Said output parameter is the local alumina concentration in the subsystem
and/or the
alumina dissolution rate and/or the local anode-cathode distance in the
subsystem.
Said input parameter is selected from the group formed by: currents of anodes
in the
subsystem, anode beam movement in the subsystem, cell voltage in the
subsystem,
alumina dumps in the subsystem, ACD change rate, and/or said input parameter
is the
output of a previous estimate of one or more of said local variables.
In an advantageous embodiment said input parameter is the individual anode
current
determined for each anode in the subsystem.
The number of subsystems (n) is advantageously chosen between 2 and 16, and is
preferably equal to 4. Said subsystems correspond to sectors of substantially
same
length, divided along the main dimension of the cell.
In an advantageous embodiment said output parameter is the local concentration
of
alumina in the bath, and said physical action comprises increasing or
decreasing the
alumina dump in the subsystem in which the estimated concentration of alumina
in the
bath is inferior or superior, respectively, to a predetermined target value.
In another advantageous embodiment, which can be combined with the previous
one,
said output parameter is the anode ¨ cathode distance, and said physical
action
comprises increasing or decreasing the anode ¨ cathode distance, when the
estimated
anode ¨ cathode distance is inferior or superior, respectively, to a
predetermined target
value.
Said method can comprise the following steps,
- measuring at least one value, called here "level 1 measured value", of said
input
parameter for the whole cell,
- obtaining at least one value, called here "level 1 estimated value", of said
output
parameter, on the basis of said level 1 measured value, using a mathematical
observer;
- dividing said cell into at least two subsystems called "level 2 subsystems",

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
7
- for each level 2 subsystem, measuring at least one value, called "level 2
measured
value", of said input parameter,
- for each level 2 subsystem, obtaining at least one value, called "level 2
estimated
value", of said output parameter, on the basis both of said level 2 measured
value
and of said level 1 estimated value, using said mathematical observer.
It can further comprise the following steps, carried out in a recursive
(cascaded) way:
- dividing said cell into at least 2n subsystems of level n,
- for each subsystem of level n: measuring at least one value, called
"level n
measured value", of said input parameter
- for each subsystem of level n: obtaining at least one value, called
"level n
estimated value", of said output parameter, on the basis both of said level n
measured value and of said level (n-1) estimated value, using said
mathematical
observer.
In an advantageous embodiment said mathematical observer is of the Kalman
filter-type.
Another object of the invention is an electrolytic cell suitable for the Hall-
Heroult
electrolysis process, said cell comprising
- a cathode forming the bottom of said electrolytic cell and comprising a
plurality of
parallel cathode blocks, each cathode block carrying at least one current
collector
bar and two electrical connections points,
- a lateral lining defining together with the cathode a volume containing
the liquid
electrolyte and the liquid metal resulting from the Hall-Heroult electrolysis
process,
said cathode and lateral lining being contained in an outer metallic shell,
- a plurality of anode assemblies suspended above the cathode, each anode
assembly comprising at least one anode and a metallic anode rod connected to
an
anode busbar (so-called "anode beam"),
- a plurality of alumina feeders by which alumina powder is fed into the
liquid bath,
and said electrolytic cell being characterized in that it comprises specific
means for
carrying out a method according to the invention.
Said specific means comprise a specifically programmed microprocessor.
In an advantageous embodiment said cell comprises means to determine
individual
anode currents for each anode.

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
8
The method according to the present invention has several advantages in view
of prior art,
amongst which:
1. The observer produces quantitative spatial estimation of state variables
based on a
dynamic model, which provides a more systematic way of utilizing anode current
measurements.
2. The observer has a flexible structure. The exact discretization of the cell
can depend on
the level of details required and the area of interests.
3. The multi-stage configuration ensures system observability (without which
the system is
not observable, which means that all the state variables cannot be estimated)
and
reduces modelling errors and uncertainties as estimations from the previous
stage are
served as additional information as well as constraints.
4. The observer is tuned properly so that it produces converging results at
different
starting conditions of reasonable ranges.
Figures
Figure 1 is a schematic view, showing an electrolytic cell for carrying a
monitoring process
according to the invention.
Figure 2 is a schematic diagram of the multi-stage state observer.
Figure 3 shows the estimated spatial alumina concentration during a time when
a feeder
is blocked on purpose.
Figure 4 shows estimated spatial alumina concentration during a time when a
feeder or
crust breaker problem has occurred.
Description
1. General presentation
An aluminium smelter plant comprises a plurality of electrolytic cells
arranged the one
behind the other (and side by side), typically along two parallel lines. These
cells are
electrically connected in series by means of conductors, so that electrolysis
current
passes from one cell to the next. The number of cells in a series is typically
comprised
between 50 and over 400, but this figure is not substantial for the present
invention. The
cells are arranged transversally in reference of main direction of the line
they constitute. In
other words the main dimension, or length, of each cell is substantially
orthogonal to the
main direction of a respective line, i.e. the circulation direction of
current.
Referring to figure 1, a Hall-Heroult electrolytic cell 1, the general
structure of which is
known per se, first comprises a cathode 2 forming the bottom of said
electrolytic cell and

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
9
comprising a plurality of parallel cathode blocks, each cathode block being
provided with
at least one current collector bar and two electrical connection ends. A
lateral lining 3
defines together with the cathode a volume V containing the liquid electrolyte
8 and the
liquid metal 9 resulting from the Hall-Heroult electrolysis process, said
cathode and lateral
lining being contained in an outer metallic potshell 4. Said electrolytic cell
further
comprises a plurality of anode assemblies suspended above the cathode, each
anode
assembly comprising at least one anode 11-18 and a metallic anode rod 6
connected to
an anode busbar 7 (so-called anode beam). In the shown example, there are two
rows of
eight anodes 11-18, only one row being illustrated. Moreover, the cell
includes four
aluminium feeders 21-24 (linked to an outside alumina supply, not shown on the
figure)
regularly provided along the main dimension of the cell, between its tap end T
and its duct
end D.
The Hall-Heroult process as such, the way to operate the latter, as well as
the cell
arrangement are known to a person skilled in the art and will not be described
here in
more detail. It is sufficient to explain that the current is fed into the
anode beam 7, flows
from the anode beam 7 to the plurality of anode rods 6 and to the anodes 11-18
in contact
with the liquid electrolyte 8 where the electrolytic reaction takes place.
Then the current
crosses the liquid metal pad 9 resulting from the process and eventually will
be collected
.. at the cathode blocks forming the cathode 2. In the present description,
the terms "upper"
and "lower" refer to mechanical elements in use, with respect to a horizontal
ground
surface. Moreover, unless otherwise specifically mentioned, "conductive" means
"electrically conductive".
In the present invention embodiment, attempt is made to estimate the local
alumina
concentration, alumina dissolution rate and average anode cathode distance
(ACD),
which are referred to as "state variables", in the above mentioned
electrolyte. This
estimation is carried out on the basis of the determination of four
parameters, i.e.
P1: anode currents, P2: alumina dumps,
P3: anode beam movement, P4: cell voltage
In view of this determination, the cell is provided with four series of
sensors or actuators,
each being relative to one respective of the above listed parameters:
S11 to S18: means to sensors determine anode current. In the framework of this
invention
anode currents can be determined using any method. In an advantageous
embodiment

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
the number of these sensors is equal to the number of anode rods and they can
be
positioned on the beam between two adjacent anode rods.
A21 to A24: alumina dumps actuators. Each of these actuators is positioned at
the outlet
of its respective feeder 21-24, and is controlling the opening and closing of
said feeder.
5 Each opening of the outlet is releasing a fixed volume of powdered
alumina into the
electrolytic bath, and the quantity of alumina fed through each feeder is
calculated from
said fixed volume and the density of alumina. We will refer here to a
"measurement" in
relation with the determination of the number of alumina dumps, although in
practice it is
usually not the mass of dumped alumina that is measured but the number alumina
dumps
10 of a volume of powder predetermined by the volume of the feeder is
counted by the
actuator.
S3: one single beam movement sensor for the whole cell.
S4: one single cell voltage sensor for the whole cell.
The method according to the invention does not depend upon the means and
methods
used for the determination of the input parameters, provided that said means
are capable
of determining said input parameters.
All the sensors and actuators are connected to a central unit U; this
connection is
symbolized as dotted lines on figure 1. Said central unit U is provided in
particular with a
calculator configured to use an extended Kalman Filter. On figure 1 the
voltage beam
sensor (measuring the anode beam height) and voltage beam actuator (modifying
the
abode beam height) is symbolized by the letter B, and the sensor measuring the
cell
voltage by the letter Z.
We describe here an embodiment of the method according to the invention, in
relation
with figure 2, where:
U
N i u s the input to the j-th observer in the i-th stage at time step N,
X
N i u s the estimation result from the j-th observer in the i-th stage at time
step N.
Time step 0
In step 0 the system is initialised. The number of stages in the cascaded
state observer is
decided. Reasonable initial estimations of the global (average) state
variables and
estimation of error covariance are made.
Time step 1
- Stage 1

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
11
The four input parameters (line current, ACD change rate (determined from
anode
consumption rate and aluminium accumulation rate), beam movement, alumina
dumps)
are determined (measured) for the whole cell. More precisely, one global value
is used for
each parameter, even if more than one value is measured; this means, for
example, that
the alumina dumps for the four feeders are summed up to become one global
value, and
the current value used here is the line current, which is the summation of all
individual
anode currents. These values serve as u111 to the observer. The estimation of
states at
time step 1 (x111) is produced using the standard extended Kalman filter
algorithm with the
initial estimation of states and error covariance. x111 contains the
estimation of average
alumina concentration in the bath, alumina dissolution rate and average ACD at
time
step 1.
In step 0, initial estimations of these variables are made, they are used to
calculate an
estimated cell voltage using equation (1). The difference between this
estimated cell
voltage and the measured cell voltage is then used to adjust the estimated
variables. After
some time (normally one feeding cycle), the estimated variables will be within
reasonable
range of the real variables.
- Stage 2
At this stage, the cell is divided into two identical subsystems, i.e. SUB1 1
and SUB1 2
(shown on figure 1).
The four input parameters are determined for the each subsystem SUB1 1 and
SUB1 2,
plus cell voltage and possibly outputs from previous state estimation stages.
ACD change
rate (determined from anode consumption rate and aluminium accumulation rate)
and
beam movement are determined (measured) for the whole cell. Local variables
(i.e.
variables that are determined for each subsystem SUB1 1 and SUB12) that are
used are
anode current and alumina dumps. More precisely, one global value is used for
each
subsystem, even if more than one value is measured. As a consequence, anode
current
in stage 2 means the summation of all individual anode current in the
subsystem, and
alumina dump in stage 2 means the summation of alumina dumps in each
subsystem.
At this stage, the filter receives two types of input data, i.e. measured
parameters of
stage 2 (u121 and u122), as well as estimated parameters of stage 1 (x111).
u121 contains the respective anode currents, cell voltage, beam movement and
alumina
dumps measured in the first subsystem, while u122 contains the respective
anode currents,
cell voltage, beam movement and alumina dumps measured in the second
subsystem.

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
12
The estimation of states in the two subsystems is obtained using the standard
extended
Kalman filter, subject to the constraint that the average of x121 and x122 is
x111, the
estimated parameters of stage 1. x121 and x122 contain the estimated alumina
concentration, alumina dissolution, rate and ACD in the two subsystems; these
are the
outputs.
It should be noted that the operation of this filter at stage 2 is different
from the one at
stage 1.
- Stage 3 and beyond
The cell is divided into further subsystems (SUB21 to SUB24 on figure 1). The
cell is
subsequently divided into subsystems and the estimation results in the
previous stage are
used in the current stage. The estimation stops when the desired number of
stages has
been reached. As in step 2, local variables that are used in each subsystem
are anode
current and alumina dumps.
Time step 2 and beyond
The standard Kalman filter recursion is applied in each stage, using the
estimation results
from previous time step as the new starting point.
In the outlined method, the estimated alumina concentration and ACD are
produced after
nth stage state observer at each time step. It is an approach which provides
online
monitoring of spatial variables of a smelter cell.
Upon the basis of the estimated values, for each parameter, appropriate
regulation of the
electrolytic cell can be carried out.
Thus, let us consider that the estimated value of alumina concentration is
lower in
subsystem SUB21 than in the other subsystems. The operator will then increase
the flow
rate of alumina (or the number of dumps of a predetermined volume of alumina
powder),
delivered by feeder 21.
Let us consider that the estimated value of anode cathode distance is lower in
subsystem
SUB21 than in the other subsystems. The operator will then adjust the anode-
cathode
distance of the anodes in the said subsystem by raising or lowering the anode

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
13
Examples
These examples present results obtained through the method according to the
invention.
Example 1
The cell has been divided into four subsystems, where zone 1 is at the tap
end, zone 2 is
in between zone 1 and zone 3, zone 4 is at the duct end and adjacent to zone
3. In this
example, a feeder in zone 2 is blocked on purpose while the total alumina feed
rate to the
cell is maintained as usual, i.e. the other feeders dump more to compensate
the blocked
feeder. The goal was to estimate the spatial variables in the four subsystems.
The cascaded state observer therefore contained three stages. Following the
procedure
described above, the spatial distribution of alumina concentration in the four
zones was
estimated and figure 3 depicts the estimated values of spatial alumina
concentration in
response to the blocked feeder. As can be seen, following the feeder blocking,
there is a
significant difference in the spatial alumina concentration in the four zones
depending on
the location. The estimated alumina concentrations in zone 1 and zone 2
decrease, while
the concentrations in zone 3 and zone 4 increase. The concentration in zone 2
is the
lowest since the feeder in this area is blocked, but due to the flow of
electrolyte, the
concentration in zone 1 is also relatively low. The same applies to the
concentration in
zone 3. As for zone 4, it is the furthest away from zone 2 and therefore it is
the least
affected by the depletion of alumina in zone 2. It causes the alumina content
in this zone
to increase, and to become the highest in the cell.
It should be noted that apart from the blocked feeder, the alumina addition
rate in the
other feeders was the same in this example. Even so, the cascaded state
observer is able
to produce the reasonable and logical estimation of spatial variables based on
the
information available.
Example 2:
In this example, the configuration of the discretised cell was the same as
that in Example
1. Figure 4 shows the estimated spatial alumina concentration in the four
zones with an
unexpected feeder or crust breaker problem, which was later discovered to be
in zone 2.
Similar to what is shown in Example 1, there is a significant difference in
the spatial
alumina concentration in the four zones towards the end of the period. The
estimated
alumina concentrations in zone 1 and zone 2 are relatively lower than the
concentrations
in zone 3 and zone 4. It indicates that there is a depletion of alumina
concentration in
zone 1 and zone 2, which may be due to the feeder/breaker problem.

CA 03012166 2018-07-20
WO 2017/141134 PCT/IB2017/050661
14
It should be noted that in this example, the cascaded state observer does not
know the
feeder/breaker problem a priori, instead it assumes the regular alumina
addition rate.
Even so, the estimation of spatial variables is able to pinpoint the
problematic area in the
cell. This allows the quick identification of the defective feeder or crust
breaker device,
and eventually speeds up the work of the maintenance team in the plant.

Representative Drawing

Sorry, the representative drawing for patent document number 3012166 was not found.

Administrative Status

2024-08-01:As part of the Next Generation Patents (NGP) transition, the Canadian Patents Database (CPD) now contains a more detailed Event History, which replicates the Event Log of our new back-office solution.

Please note that "Inactive:" events refers to events no longer in use in our new back-office solution.

For a clearer understanding of the status of the application/patent presented on this page, the site Disclaimer , as well as the definitions for Patent , Event History , Maintenance Fee  and Payment History  should be consulted.

Event History

Description Date
Grant by Issuance 2023-09-05
Letter Sent 2023-09-05
Inactive: Cover page published 2023-09-04
Pre-grant 2023-07-06
Inactive: Final fee received 2023-07-06
Notice of Allowance is Issued 2023-05-02
Letter Sent 2023-05-02
Inactive: Approved for allowance (AFA) 2023-04-21
Inactive: Q2 passed 2023-04-21
Amendment Received - Voluntary Amendment 2023-02-21
Amendment Received - Response to Examiner's Requisition 2023-02-21
Examiner's Report 2022-10-21
Inactive: Report - No QC 2022-10-06
Letter Sent 2022-01-28
All Requirements for Examination Determined Compliant 2022-01-05
Request for Examination Requirements Determined Compliant 2022-01-05
Request for Examination Received 2022-01-05
Common Representative Appointed 2020-11-08
Change of Address or Method of Correspondence Request Received 2020-01-17
Common Representative Appointed 2019-10-30
Common Representative Appointed 2019-10-30
Change of Address or Method of Correspondence Request Received 2019-08-14
Letter Sent 2018-10-19
Letter Sent 2018-10-19
Inactive: Single transfer 2018-10-15
Inactive: Cover page published 2018-08-02
Inactive: Notice - National entry - No RFE 2018-07-30
Inactive: First IPC assigned 2018-07-25
Inactive: IPC assigned 2018-07-25
Inactive: IPC assigned 2018-07-25
Inactive: IPC assigned 2018-07-25
Inactive: IPC assigned 2018-07-25
Application Received - PCT 2018-07-25
National Entry Requirements Determined Compliant 2018-07-20
Application Published (Open to Public Inspection) 2017-08-24

Abandonment History

There is no abandonment history.

Maintenance Fee

The last payment was received on 2023-02-02

Note : If the full payment has not been received on or before the date indicated, a further fee may be required which may be one of the following

  • the reinstatement fee;
  • the late payment fee; or
  • additional fee to reverse deemed expiry.

Patent fees are adjusted on the 1st of January every year. The amounts above are the current amounts if received by December 31 of the current year.
Please refer to the CIPO Patent Fees web page to see all current fee amounts.

Fee History

Fee Type Anniversary Year Due Date Paid Date
Basic national fee - standard 2018-07-20
Registration of a document 2018-10-15
MF (application, 2nd anniv.) - standard 02 2019-02-08 2019-01-31
MF (application, 3rd anniv.) - standard 03 2020-02-10 2020-01-22
MF (application, 4th anniv.) - standard 04 2021-02-08 2021-01-20
Request for examination - standard 2022-02-08 2022-01-05
MF (application, 5th anniv.) - standard 05 2022-02-08 2022-01-19
MF (application, 6th anniv.) - standard 06 2023-02-08 2023-02-02
Final fee - standard 2023-07-06
MF (patent, 7th anniv.) - standard 2024-02-08 2024-01-04
Owners on Record

Note: Records showing the ownership history in alphabetical order.

Current Owners on Record
DUBAI ALUMINIUM PJSC
NEWSOUTH INNOVATIONS PTY LIMITED
Past Owners on Record
ALI JASIM BANJAB
BARRY WELCH
CHEUK-YI CHEUNG
JIE BAO
MARIA SKYLLAS-KAZACOS
SERGEY AKHMETOV
YUCHEN YAO
Past Owners that do not appear in the "Owners on Record" listing will appear in other documentation within the application.
Documents

To view selected files, please enter reCAPTCHA code :



To view images, click a link in the Document Description column. To download the documents, select one or more checkboxes in the first column and then click the "Download Selected in PDF format (Zip Archive)" or the "Download Selected as Single PDF" button.

List of published and non-published patent-specific documents on the CPD .

If you have any difficulty accessing content, you can call the Client Service Centre at 1-866-997-1936 or send them an e-mail at CIPO Client Service Centre.


Document
Description 
Date
(yyyy-mm-dd) 
Number of pages   Size of Image (KB) 
Claims 2018-07-19 3 125
Abstract 2018-07-19 1 65
Drawings 2018-07-19 2 121
Description 2018-07-19 14 659
Claims 2023-02-20 3 171
Courtesy - Certificate of registration (related document(s)) 2018-10-18 1 106
Courtesy - Certificate of registration (related document(s)) 2018-10-18 1 106
Notice of National Entry 2018-07-29 1 194
Reminder of maintenance fee due 2018-10-09 1 112
Courtesy - Acknowledgement of Request for Examination 2022-01-27 1 424
Commissioner's Notice - Application Found Allowable 2023-05-01 1 579
Final fee 2023-07-05 6 161
Electronic Grant Certificate 2023-09-04 1 2,528
International search report 2018-07-19 3 123
Patent cooperation treaty (PCT) 2018-07-19 1 39
National entry request 2018-07-19 4 121
Request for examination 2022-01-04 5 155
Examiner requisition 2022-10-20 4 194
Amendment / response to report 2023-02-20 16 627